Xylonite (plastic)

Celluloids are a class of compounds created from nitrocellulose and camphor, with added dyes and other agents. Generally considered the first thermoplastic, it was first created as Parkesine in 1856 and as Xylonite in 1869, before being registered as Celluloid in 1870. Celluloid is easily molded and shaped, and it was first widely used as an ivory replacement.

The main use was in movie and photography film industries, which used only celluloid film stock prior to the adoption of acetate safety film in the 1950s. Celluloid is highly flammable, difficult and expensive to produce and no longer widely used; its most common uses today are in table tennis balls, musical instruments, and guitar picks.

Nitrocellulose-based plastics slightly predate celluloid. Collodion, invented in 1848 and used as a wound dressing and an emulsion for photographic plates, is dried to a celluloid-like film.

The first celluloid as a bulk material for forming objects was made in 1855 in Birmingham, England, by Alexander Parkes, who was never able to see his invention reach full fruition, after his firm went bankrupt due to scale-up costs. Parkes patented his discovery as Parkesine in 1862 after realising a solid residue remained after evaporation of the solvent from photographic collodion.

Parkes patented it as a clothing waterproofer for woven fabrics in the same year. Later Parkes showcased Parkesine at the 1862 International Exhibition in London, where he was awarded a bronze medal for his efforts. The introduction of Parkesine is generally regarded as the birth of the plastics industry. Parkesine was made from cellulose treated with nitric acid and a solvent. It is often called synthetic ivory. The Parkesine company ceased trading in 1868. Pictures of Parkesine are held by the Plastics Historical Society of London. There is a plaque on the wall of the site of the Parkesine Works in Hackney, London.

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