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Sodium orthovanadate

Sodium orthovanadate
Na3VO4dihydrate.tif
Names
IUPAC name
Sodium vanadate(V)
Other names
Sodium vanadium oxide
Identifiers
3D model (JSmol)
ECHA InfoCard 100.033.883
PubChem CID
RTECS number YW1120000
Properties
Na3VO4
Molar mass 183.908 g/mol
Appearance white powder
Density 2.16 g/cm3, solid
Melting point 858 °C (1,576 °F; 1,131 K)
22.17 g/100 mL
Solubility insoluble in ethanol
Structure
cubic
Thermochemistry
164.8 J/mol K
190 J/mol K
−1757 kJ/mol
Hazards
Main hazards Harmful.
NFPA 704
Flammability code 0: Will not burn. E.g., water Health code 3: Short exposure could cause serious temporary or residual injury. E.g., chlorine gas Reactivity code 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g., liquid nitrogen Special hazards (white): no codeNFPA 704 four-colored diamond
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
LD50 (median dose)
330 mg/kg (oral, rat)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Sodium orthovanadate is the inorganic compound with the chemical formula Na3VO4·2H2O (sodium orthovanadate dihydrate). It is a salt of the VO3−
4
oxyanion. It is a colorless, water-soluble solid.

Sodium orthovanadate is produced by dissolving vanadium(V) oxide in a solution of sodium hydroxide:

The salt features tetrahedral VO3−
4
centers linked to octahedral Na+ sites.

Acidification of orthovanadate induces condensation to polyoxovanadates, specifically decavanadate.

Vanadates exhibit a variety of biological activities, in part because they serve as structural mimics of phosphates.


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