Molecular Borromean rings

Molecular Borromean rings are an example of a mechanically-interlocked molecular architecture in which three macrocycles are interlocked in such a way that breaking any macrocycle allows the others to disassociate. They are the smallest examples of Borromean rings. The synthesis of molecular Borromean rings was reported in 2004 by the group of J. Fraser Stoddart. The so-called Borromeate is made up of three interpenetrated macrocycles formed from the reaction between 2,6-diformylpyridine and diamine compounds, complexed with zinc.

This compound was synthesized from two building blocks: 2,6-diformylpyridine (a pyridine with two aldehyde groups) and a diamine containing a 2,2'-bipyridine group. Zinc acetate is added as the template for the reaction, resulting in one zinc atom in each of a total of 6 pentacoordinate complexation sites. Trifluoroacetic acid (TFA) is added to catalyse the imine bond-forming reactions. The preparation of the tri-ring Borromeate involves a total of 18 precursor molecules and is only possible because the building blocks self-assemble through 12 aromatic pi-pi interactions and 30 zinc to nitrogen dative bonds. Because of these interactions, the Borromeate is thermodynamically the most stable reaction product out of potentially many others. As a consequence of all the reactions taking place being equilibria, the Borromeate is the predominant reaction product.

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