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Ettringite

Ettringite
Ettringite-290218.jpg
Ettringite, 3.3×2.6×2.5 cm. Kalahari manganese fields, Northern Cape Province, South Africa
General
Category Sulfate minerals
Formula
(repeating unit)
Ca6Al2(SO4)3(OH)12·26H2O
Strunz classification 7.DG.15
Crystal system Trigonal
Crystal class Ditrigonal pyramidal (3m)
H-M symbol: (3m)
Space group P31c
Unit cell a = 11.23, c = 21.44 [Å]; Z = 2
Identification
Color Colorless, pale yellow, milky white
Crystal habit Acicular growth, striated prismatic crystals; fibrous to cottonlike
Cleavage Perfect on {1010}
Mohs scale hardness 2-2.5
Luster Vitreous
Streak White
Diaphaneity Transparent to opaque
Specific gravity 1.77
Optical properties Uniaxial (-)
Refractive index nω = 1.491, nε = 1.470
Birefringence δ = 0.021
Ultraviolet fluorescence Non-fluorescent
Solubility Partially soluble in water
Alters to Partially dehydration on atmospheric exposure, becomes opaque
References

Ettringite is a hydrous calcium aluminium sulfate mineral with formula: Ca6Al2(SO4)3(OH)12·26H2O. It is a colorless to yellow mineral crystallizing in the trigonal system. The prismatic crystals are typically colorless, turning white on partial dehydration. It is part of the ettringite-group which includes other sulfates such as thaumasite and bentorite.

Ettringite was first described in 1874 by J.Lehmann, for an occurrence near the Ettringer Bellerberg volcano, Ettringen, Rheinland-Pfalz, Germany. It occurs within metamorphically altered limestone adjacent to igneous intrusive rocks or within xenoliths. It also occurs as weathering crusts on larnite in the Hatrurim Formation of Israel. It occurs associated with portlandite, afwillite and hydrocalumite at Scawt Hill, Ireland and with afwillite, hydrocalumite, mayenite and gypsum in the Hatrurim Formation. It has also been reported from the Zeilberg quarry, Maroldsweisach, Bavaria; at Boisséjour, near Clermont-Ferrand, Puy-de-Dôme, Auvergne, France; the N’Chwaning mine, Kuruman district, Cape Province, South Africa; in the US, occurrences were found in spurrite-merwinite-gehlenite skarn at the 910 level of the Commercial quarry, Crestmore, Riverside County, California and in the Lucky Cuss mine, Tombstone, Cochise County, Arizona.


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