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Acetyl

Acetyl group
Skeletal formula of acetyl with all implicit hydrogens shown
Names
IUPAC name
Acetyl (preferred to ethanoyl)
Systematic IUPAC name
Methyloxidocarbon(•) (additive)
Identifiers
3170-69-2 N
3D model (Jmol) Interactive image
Abbreviations Ac
1697938
ChEBI CHEBI:46887 YesY
ChemSpider 121499 YesY
786
PubChem 137849
Properties
C2H3O
Molar mass 43.05 g·mol−1
Thermochemistry
−15 to −9 kJ mol−1
Related compounds
Related compounds
Acetone

Carbon monoxide

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N  (what is YesYN ?)
Infobox references

Carbon monoxide

In organic chemistry, acetyl is a moiety, the acyl with chemical formula CH3CO. It is sometimes represented by the symbol Ac (not to be confused with the element actinium). The acetyl group contains a methyl group single-bonded to a carbonyl. The carbonyl center of an acyl radical has one nonbonded electron with which it forms a chemical bond to the remainder R of the molecule. In IUPAC nomenclature, acetyl is called ethanoyl, although this term is rarely heard. The acetyl moiety is a component of many organic compounds, including acetic acid, the neurotransmitter acetylcholine, acetyl-CoA, acetylcysteine, and the analgesics acetaminophen (also known as paracetamol) and acetylsalicylic acid (better known as aspirin).

The introduction of an acetyl group into a molecule is called acetylation. In biological organisms, acetyl groups are commonly transferred from acetyl-CoA to coenzyme A (CoA). Acetyl-CoA is an intermediate both in the biological synthesis and in the breakdown of many organic molecules. Acetyl-CoA is also created during the second stage of cellular respiration, the Krebs Cycle, by the action of pyruvate dehydrogenase on pyruvic acid.


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