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Thorite

Thorite
Thorite-288916.jpg
Thorite crystal from the Kemp uranium mine in Ontario (size: 2.2 x 2.2 x 1.6 cm)
General
Category Silicate mineral
Formula
(repeating unit)
(Th,U)SiO4
Strunz classification 9.AD.30
Crystal system Tetragonal
Crystal class Ditetragonal dipyramidal (4/mmm)
H-M symbol: (4/m 2/m 2/m)
Space group I41/amd
Unit cell a = 7.13, c = 6.32 [Å]; Z = 4
Identification
Color Yellow-orange, brownish yellow, brownish black, black
Crystal habit In square prisms, or pseudo-octahedral crystals; also massive
Cleavage Distinct on {110}
Fracture Conchoidal
Tenacity Brittle
Mohs scale hardness 4.5 - 5
Luster Vitreous to resinous
Streak Light orange to light brown sometimes even an alien magenta
Diaphaneity Nearly opaque, transparent in thin fragments
Specific gravity 6.63 - 7.20
Optical properties Uniaxial (-)
Refractive index nω = 1.790 - 1.840 nε = 1.780 - 1.820
Birefringence δ = 0.010 - 0.020
Alters to Commonly metamict
Other characteristics Radioactive
References

Thorite, (Th,U)SiO4, is a rare nesosilicate of thorium that crystallizes in the tetragonal system and is isomorphous with zircon and hafnon. It is the most common mineral of thorium and is nearly always strongly radioactive. It was named in 1829 to reflect its thorium content. Thorite was discovered in 1828 on the island of Løvøya, Norway, by the vicar and mineralogist, Hans Morten Thrane Esmark, who sent the first specimens of this black mineral to his father, Jens Esmark, who was a professor of mineralogy and geology.

Specimens of thorite generally come from igneous pegmatites and volcanic extrusive rocks, hydrothermal veins and contact metamorphic rocks. It is also known to occur as small grains in detrital sands. Crystals are rare, but when found can produce nicely shaped short prismatic crystals with pyramidal terminations. It is commonly associated with zircon, monazite, gadolinite, fergusonite, uraninite, yttrialite and pyrochlore.

Thorite is currently an important ore of uranium. A variety of thorite, often called "uranothorite", is particularly rich in uranium and has been a viable uranium ore at Bancroft in Ontario, Canada. Other varieties of thorite include "orangite", an orange variety, and "calciothorite", an impure variety with trace amounts of calcium.


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