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Perovskite

Perovskite
Perovskite mineral.jpg
General
Category Oxide minerals
Formula
(repeating unit)
CaTiO3
Strunz classification 4.CC.30
Crystal system Orthorhombic
Crystal class Dipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space group Pnma
Identification
Formula mass 135.96 g/mol
Color Black, reddish brown, pale yellow, yellowish orange
Crystal habit Pseudo cubic – crystals show a cubic outline
Twinning complex penetration twins
Cleavage [100] good, [010] good, [001] good
Fracture Conchoidal
Mohs scale hardness 5–5.5
Luster Adamantine to metallic; may be dull
Streak grayish white
Diaphaneity Transparent to opaque
Specific gravity 3.98–4.26
Optical properties Biaxial (+)
Refractive index nα=2.3, nβ=2.34, nγ=2.38
Other characteristics non-radioactive, non-magnetic
References

Perovskite (pronunciation: /pəˈrɒvskt/) is a calcium titanium oxide mineral composed of calcium titanate (CaTiO3). The mineral was discovered in the Ural Mountains of Russia by Gustav Rose in 1839 and is named after Russian mineralogist Lev Perovski (1792–1856).

It lends its name to the class of compounds which have the same type of crystal structure as CaTiO3 (XIIA2+VIB4+X2−3) known as the perovskite structure. The perovskite crystal structure was first described by Victor Goldschmidt in 1926, in his work on tolerance factors. The crystal structure was later published in 1945 from X-ray diffraction data on barium titanate by Helen Dick Megaw.

Found in the Earth’s mantle, perovskite’s occurrence at Khibina Massif is restricted to the under-saturated ultramafic rocks and foidolites, due to the instability in a paragenesis with feldspar. Perovskite occurs as small anhedral to subhedral crystals filling interstices between the rock-forming silicates.


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