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Pentyl

Pentyl radical
Skeletal formula of pentyl with all explicit hydrogens added
Identifiers
2672-01-7
3D model (Jmol) Interactive image
ChemSpider 109782 YesY
PubChem 123167
Properties
C
5
H
11
Molar mass 71.1408 g mol−1
Reacts
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

In organic chemistry, pentyl is a five-carbon alkyl functional group (substituent) with chemical formula -C5H11. It is the substituent form of the alkane pentane.

In older literature, the common non-systematic name amyl was often used for the pentyl group. Conversely, the name pentyl was used for several five-carbon branched alkyl groups, distinguished by various prefixes.

A cyclopentyl group is a ring with the formula -C5H9.

The name is also used for the pentyl radical, a pentyl group as an isolated molecule. This free radical is only observed in extreme conditions. Its formula is often written "C
5
H
11
•" or "•C
5
H
11
" to indicate that it has one unsatisfied valence bond.

The following names are still used sometimes:

The free radical pentyl was studied by Pacansky and Gutierrez in 1983. The radical was obtained by exposing bishexanoyl peroxide trapped in frozen argon to ultraviolet light, that caused its decomposition into two carbon dioxide (CO
2
) molecules and two pentyl radicals.


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