Oxyhydrogen

Oxyhydrogen is a mixture of hydrogen (H₂) and oxygen (O₂) gases. This gaseous mixture is used for torches to process refractory materials and was the first gaseous mixture used for welding. Theoretically, a ratio of 2:1 hydrogen:oxygen is enough to achieve maximum efficiency; in practice a ratio 4:1 or 5:1 is needed to avoid an oxidizing flame.

This mixture may also be referred to as Knallgas (Scandinavian and German : "bang-gas"), although some authors define knallgas to be a generic term for the mixture of fuel with the precise amount of oxygen required for complete combustion, thus 2:1 oxyhydrogen would be called "hydrogen-knallgas".

Brown's gas and HHO are fringe science terms for a 2:1 mixture of oxyhydrogen obtained under certain special conditions; its proponents claim that it has special properties.

Oxyhydrogen will combust when brought to its autoignition temperature. For the stoichiometric mixture, 2:1 hydrogen:oxygen, at normal atmospheric pressure, autoignition occurs at about 570 °C (1065 °F). The minimum energy required to ignite such a mixture with a spark is about 20 microjoules. At standard temperature and pressure, oxyhydrogen can burn when it is between about 4% and 95% hydrogen by volume.

When ignited, the gas mixture converts to water vapor and releases energy, which sustains the reaction: 241.8 kJ of energy (LHV) for every mole of H₂ burned. The amount of heat energy released is independent of the mode of combustion, but the temperature of the flame varies. The maximum temperature of about 2,800 °C (5,100 °F) is achieved with an exact stoichiometric mixture, about 700 °C (1,300 °F) hotter than a hydrogen flame in air. When either of the gases are mixed in excess of this ratio, or when mixed with an inert gas like nitrogen, the heat must spread throughout a greater quantity of matter and the temperature will be lower.

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