Mercury fulminate

Mercury(II) fulminate

${\displaystyle {\ce {^{-}O-{\overset {+}{N}}{\equiv }C-Hg-C{\equiv }{\overset {+}{N}}-O^{-}}}}$
Names
Other names Fulminated Mercury
Identifiers
CAS Number	628-86-4 N
3D model (Jmol)	Interactive image
ChEBI	CHEBI:39152 Y
ChemSpider	9197626 Y
ECHA InfoCard	100.010.053
PubChem CID	11022444
InChI InChI=1S/2CNO.Hg/c2*1-2-3; Y Key: MHWLNQBTOIYJJP-UHFFFAOYSA-N Y InChI=1/2CNO.Hg/c2*1-2-3;/rC2HgN2O2/c6-4-1-3-2-5-7 Key: MHWLNQBTOIYJJP-HZIBCBEIAJ
SMILES [O-][N+]#C[Hg]C#[N+][O-]
Properties
Chemical formula	C2N2O2Hg
Molar mass	284.624 g/mol
Appearance	Grey, Pale Brown, or White Crystalline solid
Density	4.42 g/cm3
Melting point	160 °C (320 °F; 433 K)
Boiling point	356.6 °C (673.9 °F; 629.8 K)
Solubility in water	slightly soluble
Solubility	soluble in ethanol, ammonia
Explosive data
Shock sensitivity	High
Friction sensitivity	High
Detonation velocity	4250 m/s
Hazards
Main hazards	Highly Toxic, Shock Sensitive Explosive
Autoignition temperature	170 °C (338 °F; 443 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N  (what is YN ?)
Infobox references

Mercury(II) fulminate, or Hg(CNO)₂, is a primary explosive. It is highly sensitive to friction and shock and is mainly used as a trigger for other explosives in percussion caps and blasting caps. Mercury(II) cyanate, though its empirical formula is identical, has a different atomic arrangement; the cyanate and fulminate anions are isomers.

First used as a priming composition in small copper caps beginning in the 1820s, mercury fulminate quickly replaced flints as a means to ignite black powder charges in muzzle-loading firearms. Later, during the late 19th century and most of the 20th century, mercury fulminate or potassium chlorate became widely used in primers for self-contained rifle and pistol ammunition. Mercury fulminate has the distinct advantage over potassium chlorate of being non-corrosive, but it is known to weaken with time, by decomposing into its constituent elements. The reduced mercury which results forms amalgams with cartridge brass, weakening it, as well. Today, mercury fulminate has been replaced in primers by more efficient chemical substances. These are non-corrosive, less toxic and more stable over time; they include lead azide, lead styphnate and tetrazene derivatives. In addition, none of these compounds require mercury for manufacture, supplies of which can be unreliable in wartime.