Spodumene | |
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Walnut Hill Pegmatite Prospect, Huntington, Hampshire County, Massachusetts, US (Size: 14.2 x 9.2 x 3.0 cm)
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General | |
Category | Silicate mineral, pyroxene |
Formula (repeating unit) |
lithium aluminium silicate, LiAl(SiO3)2 |
Crystal system | Monoclinic |
Crystal class | Prismatic (2/m) (same H-M symbol) |
Space group | C2/c |
Unit cell | a = 9.46 Å, b = 8.39 Å c = 5.22 Å β = 110.17°; Z = 4 |
Identification | |
Color | Highly variable: white, colorless, gray, pink, lilac, violet, yellow and green, may be bicolored; emerald green - hiddenite; lilac - kunzite; yellow - triphane |
Crystal habit | prismatic, generally flattened and elongated, striated parallel to {100}, commonly massive |
Twinning | Common on {100} |
Cleavage | Perfect prismatic, two directions {110} ∧ {110} at 87° |
Fracture | Uneven to subconchoidal |
Tenacity | Brittle |
Mohs scale hardness | 6.5–7 |
Luster | Vitreous, pearly on cleavage |
Streak | white |
Specific gravity | 3.03–3.23 |
Optical properties | Biaxial (+) |
Refractive index | nα = 1.648–1.661 nβ = 1.655–1.670 nγ = 1.662–1.679 |
Birefringence | δ = 0.014–0.018 |
Pleochroism | Strong in kunzite: α-purple, γ-colorless; hiddenite: α-green, γ-colorless |
2V angle | 54° to 69° |
Fusibility | 3.5 |
Solubility | insoluble |
Other characteristics | Tenebrescence, chatoyancy, kunzite often fluorescent under UV |
References |
Spodumene is a pyroxene mineral consisting of lithium aluminium inosilicate, LiAl(SiO3)2, and is a source of lithium. It occurs as colorless to yellowish, purplish, or lilac kunzite (see below), yellowish-green or emerald-green hiddenite, prismatic crystals, often of great size. Single crystals of 14.3 m (47 ft) in size are reported from the Black Hills of South Dakota, United States.
The normal low-temperature form α-spodumene is in the monoclinic system whereas the high-temperature β-spodumene crystallizes in the tetragonal system. The normal α-spodumene converts to β-spodumene at temperatures above 900 °C. Crystals are typically heavily striated parallel to the principal axis. Crystal faces are often etched and pitted with triangular markings.
Spodumene was first described in 1800 for an occurrence in the type locality in Utö, Södermanland, Sweden. It was discovered by Brazilian naturalist Jose Bonifacio de Andrada e Silva. The name is derived from the Greek spodumenos (σποδυμενος), meaning "burnt to ashes," owing to the opaque, ash-grey appearance of material refined for use in industry.
Spodumene occurs in lithium-rich granite pegmatites and aplites. Associated minerals include: quartz, albite, petalite, eucryptite, lepidolite and beryl.