Chatoyancy

In gemology, chatoyancy (/ʃəˈtɔɪ.ənsi/ shə-TOY-ən-see), or chatoyance or cat's eye effect, is an optical reflectance effect seen in certain gemstones. Coined from the French "œil de chat", meaning "cat's eye", chatoyancy arises either from the fibrous structure of a material, as in tiger's eye quartz, or from fibrous inclusions or cavities within the stone, as in cat's eye chrysoberyl. The precipitates that cause chatoyance in chrysoberyl are the mineral rutile, composed mostly of titanium dioxide. Examined samples have yielded no evidence of tubes or fibres. The rutile precipitates all align perpendicularly with respect to cat's eye effect. It is reasoned that the lattice parameter of the rutile matches only one of the three orthorhombic crystal axes of the chrysoberyl, resulting in preferred alignment along that direction.

The effect can be likened to the sheen off a spool of silk: The luminous streak of reflected light is always perpendicular to the direction of the fibres. For a gemstone to show this effect best it must be cut en cabochon, with the fibers or fibrous structures parallel to the base of the finished gem. The best finished specimens show a single sharply defined band of light that moves across the stone when it is rotated. Chatoyant stones of lesser quality display a banded effect as is typical with cat's-eye varieties of quartz. Faceted stones do not show the effect well.

Gem species known for this phenomenon include the aforementioned quartz, chrysoberyl, beryl (especially var. aquamarine), charoite, tourmaline, labradorite, selenite, feldspar, apatite, moonstone, thomsonite and scapolite amongst others. Glass optical cable can also display chatoyancy if properly cut, and has become a popular decorative material in a variety of vivid colors.

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