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Gallium suboxide

Gallium(I) oxide
Names
Other names
gallium suboxide
digallium monoxide
Identifiers
ChemSpider
Properties
Ga2O
Molar mass 155.445 g/mol
Appearance brown powder
Density 4.77 g/cm3
Melting point >800 °C (decomposes)
-34·10−6 cm3/mol
Thermochemistry
−356.2 kJ/mol
Hazards
not listed
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Gallium(I) oxide or gallium suboxide is an inorganic compound with the formula Ga2O.

Gallium(I) oxide can be produced by reacting gallium(III) oxide with heated gallium in vacuum:

It can also be obtained by reacting gallium with carbon dioxide in vacuum at 850 °C.

Gallium(I) oxide is a by-product in the production of gallium arsenide wafers:

Gallium(I) oxide is a brown-black diamagnetic solid which is resistant to further oxidation in dry air. It starts decomposing upon heating at temperatures above 500 °C, and the decomposition rate depends on the atmosphere (vacuum, inter gas, air).


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