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Names | |||
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IUPAC name
1,2-Dichloroethane
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Other names
Ethylene dichloride
DCE DCA Ethane dichloride Dutch liquid, Dutch oil Freon 150 |
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Identifiers | |||
107-06-2 | |||
3D model (Jmol) | Interactive image | ||
ChEBI | CHEBI:27789 | ||
ChEMBL | ChEMBL16370 | ||
ChemSpider | 13837650 | ||
ECHA InfoCard | 100.003.145 | ||
KEGG | C06752 | ||
PubChem | 11 | ||
RTECS number | KI0525000 | ||
UNII | 55163IJI47 | ||
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Properties | |||
C2H4Cl2 | |||
Molar mass | 98.95 g·mol−1 | ||
Appearance | Colorless liquid | ||
Odor | characteristic, pleasant chloroform-like odor | ||
Density | 1.253 g/cm3, liquid | ||
Melting point | −35 °C (−31 °F; 238 K) | ||
Boiling point | 84 °C (183 °F; 357 K) | ||
0.87 g/100 mL (20 °C) | |||
Viscosity | 0.84 mPa·s at 20 °C | ||
Structure | |||
1.80 D | |||
Hazards | |||
Main hazards | Toxic, flammable, carcinogenic | ||
Safety data sheet | See: data page | ||
R-phrases | R11 R45 R36/37/38 | ||
S-phrases | S45 S53 | ||
NFPA 704 | |||
Flash point | 13 °C (55 °F; 286 K) | ||
Explosive limits | 6.2%-16% | ||
Lethal dose or concentration (LD, LC): | |||
LC50 (median concentration)
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3000 ppm (guinea pig, 7 hr) 1000 ppm (rat, 7 hr) |
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LCLo (lowest published)
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1217 ppm (mouse, 2 hr) 1000 ppm (rat, 4 hr) 3000 ppm (rabbit, 7 hr) |
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US health exposure limits (NIOSH): | |||
PEL (Permissible)
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TWA 50 ppm C 100 ppm 200 ppm [5-minute maximum peak in any 3 hours] | ||
REL (Recommended)
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Ca TWA 1 ppm (4 mg/m3) ST 2 ppm (8 mg/m3) | ||
IDLH (Immediate danger)
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Ca [50 ppm] | ||
Related compounds | |||
Related haloalkanes
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Methyl chloride Methylene chloride 1,1,1-Trichloroethane |
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Related compounds
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Ethylene Chlorine Vinyl chloride |
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Supplementary data page | |||
Refractive index (n), Dielectric constant (εr), etc. |
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Thermodynamic
data |
Phase behaviour solid–liquid–gas |
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UV, IR, NMR, MS | |||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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what is ?) | (|||
Infobox references | |||
The chemical compound 1,2-dichloroethane commonly known as ethylene dichloride (EDC), is a chlorinated hydrocarbon. It is a colourless liquid with a chloroform-like odour. The most common use of 1,2-dichloroethane is in the production of vinyl chloride, which is used to make polyvinyl chloride (PVC) pipes, furniture and automobile upholstery, wall coverings, housewares, and automobile parts.1,2-Dichloroethane is also used generally as an intermediate for other organic chemical compounds and as a solvent. It forms azeotropes with many other solvents, including water (b.p. 70.5 °C) and other chlorocarbons.
In 1794, physician Jan Rudolph Deiman, merchant Adriaan Paets van Troostwijk, chemist Anthoni Lauwerenburg, and botanist Nicolaas Bondt, under the name of Gezelschap der Hollandsche Scheikundigen (Dutch: Society of Dutch Chemists), were the first to produce 1,2-dichloroethane from olefiant gas (oil-making gas, ethylene) and chlorine gas. Although the Gezelschap in practice did not do much in-depth scientific research, they and their publications were highly regarded. Part of that acknowledgement is that 1,2-dichloroethane was called "Dutch oil" in old chemistry.
Nearly 20 million tons of 1,2-dichloroethane are produced in the United States, Western Europe, and Japan. Production is primarily achieved through the iron(III) chloride-catalysed reaction of ethene (ethylene) and chlorine.
1,2-dichloroethane is also generated by the copper(II) chloride-catalysed oxychlorination of ethylene: