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Cumene process


The cumene process (cumene-phenol process, Hock process) is an industrial process for developing phenol and acetone from benzene and propylene. The term stems from cumene (isopropyl benzene), the intermediate material during the process. It was invented by Heinrich Hock in 1944 and independently by R. Ūdris and P. Sergeyev in 1942 (USSR).

This process converts two relatively cheap starting materials, benzene and propylene, into two more valuable ones, phenol and acetone. Other reactants required are oxygen from air and small amounts of a radical initiator. Most of the worldwide production of phenol and acetone is now based on this method. In 2003, nearly 7 million tonnes of phenol was produced by the cumene process. In order for this process to be economical, there must also be demand for the acetone by-product as well as the phenol.

Benzene and propylene are compressed together to a pressure of 30 standard atmospheres at 250 °C (482 °F) in presence of a catalytic Lewis acid. Phosphoric acid is often favored over aluminium halides. Cumene is formed in the gas-phase Friedel-Crafts alkylation of benzene by propylene:

Cumene is oxidized in air which removes the tertiary benzylic hydrogen from cumene and hence forms a cumene radical:


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