Chemical oxygen generator

A chemical oxygen generator is a device that releases oxygen via a chemical reaction. The oxygen source is usually an inorganic superoxide,chlorate, or perchlorate; ozonides are a promising group of oxygen sources. The generators are usually ignited by a firing pin, and the chemical reaction is usually exothermic, making the generator a potential fire hazard. Potassium superoxide was used as an oxygen source on early manned missions of the Soviet space program, for firefighters, and for mine rescue.

Commercial aircraft provide emergency oxygen to passengers to protect them from drops in cabin pressure. Chemical oxygen generators are not used for the cockpit crew, who are typically supplied using compressed oxygen canisters also known as oxygen bottles. In narrow body airliners, for each row of seats there are overhead oxygen masks and oxygen generators. In some wide-body airliners, such as the DC-10 and IL-96, the canisters and oxygen masks are mounted in the top portion of the seat backs, since the ceiling is too high above the passengers. If a decompression occurs, the panels are opened either by an automatic pressure switch or by a manual switch, and the masks are released. When the passengers pull down on the mask they remove the retaining pins and trigger the production of oxygen.

The oxidizer core is sodium chlorate (NaClO₃), which is mixed with less than 5 percent barium peroxide (BaO₂) and less than 1 percent potassium perchlorate (KClO₄). The explosives in the percussion cap are a lead styphnate and tetrazene explosive mixture. The chemical reaction is exothermic and the exterior temperature of the canister will reach 260 °C (500 °F). It will produce oxygen for 12 to 22 minutes. The two-mask generator is approximately 63 mm (2.5 in) in diameter and 223 mm (8.8 in) long. The three-mask generator is approximately 70 mm (2.8 in) in diameter and 250 mm (9.8 in) long.

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