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Calcium carbonate

Calcium carbonate
Calcium carbonate.png
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Names
IUPAC name
Calcium carbonate
Other names
Identifiers
471-34-1 YesY
3D model (Jmol) Interactive image
Interactive image
ChEBI CHEBI:3311 YesY
ChEMBL ChEMBL1200539 N
ChemSpider 9708 YesY
ECHA InfoCard 100.119.341
EC Number 207-439-9
E number E170 (colours)
KEGG D00932 YesY
PubChem 10112
RTECS number FF9335000
UNII H0G9379FGK YesY
Properties
CaCO3
Molar mass 100.0869 g/mol
Appearance Fine white powder; chalky taste
Odor odorless
Density 2.711 g/cm3 (calcite)
2.83 g/cm3 (aragonite)
Melting point 1,339 °C (2,442 °F; 1,612 K) (calcite)
825 °C (1517 °F; 1,098 K) (aragonite)
Boiling point decomposes
0.013 g/L (25 °C)
3.3×109
Solubility in dilute acids soluble
Acidity (pKa) 9.0
-38.2·10−6 cm3/mol
1.59
Structure
Trigonal
32/m
Thermochemistry
93 J·mol−1·K−1
−1207 kJ·mol−1
Pharmacology
A02AC01 (WHO) A12AA04 (WHO)
Hazards
Safety data sheet ICSC 1193
NFPA 704
Flammability code 0: Will not burn. E.g., water Health code 0: Exposure under fire conditions would offer no hazard beyond that of ordinary combustible material. E.g., sodium chloride Reactivity code 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g., liquid nitrogen Special hazards (white): no codeNFPA 704 four-colored diamond
Flash point 825 °C (1,517 °F; 1,098 K)
Lethal dose or concentration (LD, LC):
LD50 (median dose)
6450 mg/kg (oral, rat)
US health exposure limits (NIOSH):
PEL (Permissible)
TWA 15 mg/m3 (total) TWA 5 mg/m3 (resp)
Related compounds
Other anions
Calcium bicarbonate
Other cations
Magnesium carbonate
Strontium carbonate
Barium carbonate
Related compounds
Calcium sulfate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N  (what is YesYN ?)
Infobox references

Calcium carbonate is a chemical compound with the formula CaCO3. It is a common substance found in rocks as the minerals calcite and aragonite (most notably as limestone, which contains both of those minerals) and is the main component of pearls and the shells of marine organisms, snails, and eggs. Calcium carbonate is the active ingredient in agricultural lime and is created when calcium ions in hard water react with carbonate ions to create limescale. It is medicinally used as a calcium supplement or as an antacid, but excessive consumption can be hazardous.

Calcium carbonate shares the typical properties of other carbonates. Notably,

Calcium carbonate will react with water that is saturated with carbon dioxide to form the soluble calcium bicarbonate.

This reaction is important in the erosion of carbonate rock, forming caverns, and leads to hard water in many regions.

An unusual form of calcium carbonate is the hexahydrate, ikaite, CaCO3·6H2O. Ikaite is stable only below 6 °C.

The vast majority of calcium carbonate used in industry is extracted by mining or quarrying. Pure calcium carbonate (e.g. for food or pharmaceutical use), can be produced from a pure quarried source (usually marble).


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Wikipedia

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