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Zinc fluoride

Zinc fluoride
Zinc fluoride
Names
Other names
Zinc difluoride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.092
PubChem CID
RTECS number ZH3200000
Properties
ZnF2
Molar mass 103.406 g/mol (anhydrous)
175.45 g/mol (tetrahydrate)
Appearance white needles
hygroscopic
Density 4.95 g/cm3 (anhydrous)
2.30 g/cm3 (tetrahydrate)
Melting point 872 °C (1,602 °F; 1,145 K) (anhydrous)
100 °C, decomposes (tetrahydrate)
Boiling point 1,500 °C (2,730 °F; 1,770 K) (anhydrous)
.000052 g/100 mL (anhydrous)
1.52 g/100 mL, 20 °C (tetrahydrate)
Solubility sparingly soluble in HCl, HNO3, ammonia
−38.2·10−6 cm3/mol
Structure
tetragonal (anhydrous), tP6
P42/mnm, No. 136
Hazards
NFPA 704
Flammability code 0: Will not burn. E.g., water Health code 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g., chloroform Reactivity code 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g., calcium Special hazards (white): no codeNFPA 704 four-colored diamond
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Zinc fluoride (ZnF2) is an inorganic chemical compound. It is encountered as the anydrous form and also as the tetrahydrate, ZnF2 · 4H2O (rhombohedral crystal structure). It has a high melting point and has the rutile structure containing 6 coordinate zinc, which suggests appreciable ionic character in its chemical bonding. Unlike the other zinc halides, ZnCl2, ZnBr2 and ZnI2, it is not very soluble in water.

Zinc fluoride can be synthesized several ways.

Zinc fluoride can be hydrolysed by hot water to form the zinc hydroxyfluoride, Zn(OH)F.



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