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Yellowcake

Yellowcake
Yellowcake.jpg
Names
Other names
urania
Identifiers
1344-57-6 YesY
Properties
variable, see text
Appearance Yellow granules (as Yellowcake); Brown or black granules (UO2 and others)
Melting point 2,880 °C (5,220 °F; 3,150 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
YesY  (what is YesYN ?)
Infobox references

Yellowcake (also called urania) is a type of uranium concentrate powder obtained from leach solutions, in an intermediate step in the processing of uranium ores. It is a step in the processing of uranium after it has been mined but before fuel fabrication or enrichment. Yellowcake concentrates are prepared by various extraction and refining methods, depending on the types of ores. Typically, yellowcakes are obtained through the milling and chemical processing of uranium ore forming a coarse powder that has a pungent odor, is insoluble in water, and contains about 80% uranium oxide, which melts at approximately 2880 °C.

The ore is first crushed to a fine powder by passing raw uranium ore through crushers and grinders to produce "pulped" ore. This is further processed with concentrated acid, alkaline, or peroxide solutions to leach out the uranium. Yellowcake is what remains after drying and filtering. The yellowcake produced by most modern mills is actually brown or black, not yellow; the name comes from the color and texture of the concentrates produced by early mining operations.

Initially, the compounds formed in yellowcakes were not identified; in 1970, the U.S. Bureau of Mines still referred to yellowcakes as the final precipitate formed in the milling process and considered it to be ammonium diuranate or sodium diuranate. The compositions were variable and depended upon the leachant and subsequent precipitating conditions. The compounds identified in yellowcakes include uranyl hydroxide, uranyl sulfate, sodium para-uranate, and uranyl peroxide, along with various uranium oxides. Modern yellowcake typically contains 70% to 90% triuranium octoxide (U3O8) by weight. Other oxides such as uranium dioxide (UO2) and uranium trioxide (UO3) exist.


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