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Vanadium(III) nitride

Vanadium nitride
NaCl polyhedra.png
Names
IUPAC name
Vanadium nitride
Other names
Vanadium(III) nitride
Identifiers
ECHA InfoCard 100.042.151
PubChem CID
Properties
VN
Molar mass 64.9482 g/mol
Appearance black powder
Density 6.13 g/cm3
Melting point 2,050 °C (3,720 °F; 2,320 K)
Structure
cubic, cF8
Fm3m, No. 225
Hazards
Flash point Non-flammable
Related compounds
Other anions
vanadium(III) oxide, vanadium carbide
Other cations
titanium nitride, chromium(III) nitride, niobium nitride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
YesY  (what is YesYN ?)
Infobox references

Vanadium nitride, VN, is a chemical compound of vanadium and nitrogen.

Vanadium nitride is formed during the nitriding of steel and increases wear resistance. Another phase, V2N, also referred to as vanadium nitride, can be formed along with VN during nitriding. VN has a cubic, rock-salt structure. There is also a low-temperature form, which contains V4 clusters. The low-temperature phase results from a dynamic instability, when the energy of vibrational modes in the high-temperature NaCl-structure phase, are reduced below zero.

It is a strong-coupled superconductor. Nanocrystalline vanadium nitride has been claimed to have potential for use in supercapacitors.


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