Tripodal ligand
Tripodal ligands are tri- and tetradentate ligands with C3symmetry. They are popular in research in the areas of coordination chemistry and homogeneous catalysis. Because the ligands are polydentate, they do not readily dissociate from the metal centre.
When used in coordination complexes with an octahedral molecular geometry the tridentate tripod ligands occupy one face, leading to a fixed facial (or fac) geometry. The tetradentate tripodal ligands occupy four contiguous sites, leaving two cis positions available on the octahedral metal center. When bound to four- and five-coordinate metal centres, these ligands impose C3 symmetry, which can lead to uncommon ligand field splitting patterns. Tripodal ligands are often able to coordinately saturate metal ions with lower coordination numbers.
One tripodal ligand of commercial significance is nitrilotriacetate, N(CH2CO2−)3 because it is cheaply produced and has a high affinity for divalent metal ions. Other tripodal ligands include tren (N(CH2CH2NH2)3) and certain triphosphines such as RC(CH2PPh2)3. Many kinds of donor groups have been incorporated into the arms of these ligands, including amido (R2N−), and N-heterocyclic carbenes.
A tripodal triphosphine, X can be CR, SiR, Si−, BR−, B, N, P etc.
Tris(2-pyridylmethyl)amine, a tetradentate tripodal ligand popular in bioinorganic chemistry.
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