Titanium methoxide
 Abbreviated structure of titanium(IV) ethoxide. The ethoxide ligands are represented by O's. The terminal ethoxide ligands are designated by Oa, the doubly bridging ligands by Ob, and the triply bridging ligands by Oc.
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| Names | |
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IUPAC name
ethanolate; titanium(4+)
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Systematic IUPAC name
titanium(4+) tetraethanolate
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| Other names
Ethyl titanate, tetraethyl titanate
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| Identifiers | |
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3D model (JSmol)
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| ChemSpider | |
| ECHA InfoCard | 100.019.464 |
| EC Number | 221-410-8 |
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PubChem CID
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| Properties | |
| C32H80O16Ti4 | |
| Molar mass | 228.109 g/mol |
| Appearance | colorless liquid |
| Density | 1.088 |
| Boiling point | 150–152 (@10 mmHg) |
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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| Infobox references | |
Titanium ethoxide is a chemical compound with the formula Ti4(OCH2CH3)16. It is a colorless liquid that is soluble in organic solvents but hydrolyzes readily. It is sold commercially as a colorless solution. Alkoxides of titanium(IV) and zirconium(IV) are used in organic synthesis and materials science. They adopt more complex structures than suggested by their empirical formulas.
Titanium ethoxide is prepared by treating titanium tetrachloride with ethanol in the presence of an amine:
The purity of titanium ethoxide is commonly assayed by proton NMR spectroscopy. Zr(OEt)41H NMR (60 MHz, benzene-d6, ppm): 8.64 (triplet, 12H, CH3), 5.73 (quartet, 8H, CH2). Ti(OEt)4 1H NMR (90 MHz, chloroform-d, ppm): 4.36 (quartet, 8H, CH2), 1.27 (triplet, 12H, CH3).
Both Ti(OEt)4 exist mainly as tetramers with an octahedral coordination environment around the metal centers There are two types of titanium centers, depending on the number of terminal vs bridging alkoxide ligands. Zr(OEt)4 is structurally similar. Zirconium ethoxide is sold commercially as a mixture of the trimer and the tetramer. The virtual symmetry of the M4O16 core structure for the tetramer structures of these compounds is C2h.
Like the ethoxide, titanium methoxide Ti(OMe)4 exists as a tetramer with each of the TiIV metal centers having an octahedral coordination environment.
With bulky alky groups, Ti(OiPr)4 in contrast exist as a monomer with a tetrahedral environment around the Ti center. This lower degree of coordination to the metal center is attributed to the steric bulk of the iPr groups versus the n-alkyl groups, this serves to prevent bridging interactions between the metal centers.
Zirconium ethoxide can be prepared in a manner similar but not identical to the titanium compound:
A more common synthesis for zirconium ethoxide is to treat zirconium tetrachloride with the desired alcohol and ammonia:
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