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Tin tetraiodide

Tin(IV) iodide
Photograph of a sample of tin tetraiodide
Ball-and-stick model of the unit cell of tin tetraiodide
Structure and dimensions of the tin(IV) iodide molecule
Ball-and-stick model of the tin(IV) iodide molecule
Names
IUPAC name
tin(IV) iodide
Other names
tin tetraiodide
stannic iodide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.281
EC Number 232-208-4
PubChem CID
Properties
SnI4
Molar mass 626.328 g mol−1
Appearance red-orange solid
Density 4.56 g cm−3
Melting point 143 °C (289 °F; 416 K)
Boiling point 348.5 °C (659.3 °F; 621.6 K)
2.106
Structure
Cubic, cP40
P-43m, No. 205
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Tin(IV) iodide, also known as stannic iodide, is the chemical compound with the formula SnI4. This tetrahedral molecule crystallises as a bright orange solid that dissolves readily in nonpolar solvents such as benzene.

The compound is usually prepared by the reaction of iodine and tin:

The compound hydrolyses in water. In aqueous hydroiodic acid, it reacts to form a rare example of a metal hexaiodide:


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