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Thiete

Thiete
Thietene.png
Names
IUPAC name
2H-thiete
Identifiers
3D model (Jmol)
ChemSpider
PubChem CID
Properties
C3H4S
Molar mass 72.12886
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N  (what is YesYN ?)
Infobox references

Thiete is a heterocyclic compound containing an unsaturated four-membered ring with three carbon atoms and one sulfur atom. It is more commonly encountered not on its own, but in anellated derivatives, several of which have been synthesized. Thietes are generally not very stable.

Thiete is a valence isomer of the unknown compound thioacrolein (CH2=CHCH=S) Thiete has been shown to be planar, with a C-S-C angle of 76.8 degrees.

Benzothietes are thietes annulated to benzo group. Such species are prepared by flash vacuum pyrolysis of 2-mercaptobenzyl alcohols. They are precursors to other S-heterocycles.

Thiete 1,1-dioxides are sulfones, the parent being C3H4SO2. They are more stable than the parent thietes. Substituted thiete-1,1-dioxides can also be prepared by [2+2] cycloaddition of sulfenes and ynamines.


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