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Tellurium tetraiodide

Tellurium tetraiodide
Names
Other names
tellurium(IV) iodide
Identifiers
3D model (JSmol)
ECHA InfoCard 100.029.282
EC Number 232-210-5
PubChem CID
Properties
TeI4
Molar mass 635.218 g/mol
Appearance black crystals
Density 5.05 g/cm³, solid
Melting point 280 °C (536 °F; 553 K)
Structure
orthorhombic
Hazards
not listed
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
YesY  (what is YesYN ?)
Infobox references

Tellurium tetraiodide (TeI4) is an inorganic chemical compound. It has a tetrameric structure which is different from the tetrameric solid forms of TeCl4 and TeBr4. In TeI4 the Te atoms are octahedrally coordinated and edges of the octahedra are shared.

TeI4 can be prepared from the elements or by reacting Te and iodomethane, CH3I. In the vapour TeI4 dissociates:

It is a conductor when molten, dissociating into the ions TeI3+ and I. In solvents with donor properties such as acetonitrile, CH3CN ionic complexes are formed which make the solution conducting:



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