Tannin-stained waters

A blackwater river is a type of river with a deep, slow-moving channel flowing through forested swamps or wetlands. As vegetation decays, tannins leach into the water, making a transparent, acidic water that is darkly stained, resembling tea or black coffee. Most major blackwater rivers are in the Amazon Basin and the Southern United States. The term is used in fluvial studies, geology, geography, ecology, and biology. Not all dark rivers are blackwater in that technical sense. Some rivers in temperate regions, which drain or flow through areas of dark black loam, are simply black due to the color of the soil; these rivers are black mud rivers. There are also black mud estuaries.

Blackwater rivers are lower in nutrients than whitewater rivers and have ionic concentrations higher than rainwater. The unique conditions lead to flora and fauna that differ both from whitewater and clearwater rivers. Where the water types combine is attractive to a diverse group of organisms. The classification of Amazonian rivers into black, clear and whitewater was first proposed by Alfred Russel Wallace in 1853 based on water colour, but the types were more clearly defined by chemistry and physics by Harald Sioli in the 1950s and 1960s. Although many Amazonian rivers fall clearly into one of these categories, others show a mix of characteristics.

Black and white waters differ significantly in their ionic composition, as shown in Table 1. Black waters are more acidic, resulting in an aluminum concentration greater than that of the more neutral white waters. The major difference is the concentrations of sodium, magnesium, calcium and potassium; these are very low in black waters. This has ecological implications. Some animals need more calcium than is available in blackwaters, so for example, snails, which need much calcium to build shells, are not abundant in blackwaters. The lack of dissolved ions in black waters results in a low conductivity, similar to that of rainwater.

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