In 1851, George Gabriel Stokes derived an expression, now known as Stokes' law, for the frictional force – also called drag force – exerted on spherical objects with very small Reynolds numbers (i.e. very small particles) in a viscous fluid. Stokes' law is derived by solving the Stokes flow limit for small Reynolds numbers of the Navier–Stokes equations.
The force of viscosity on a small sphere moving through a viscous fluid is given by:
where:
In SI units, Fd is given in Newtons, η in Pa·s, r in meters, and v in m/s.
Stokes' law makes the following assumptions for the behavior of a particle in a fluid:
Note that for molecules Stokes' law is used to define their Stokes radius.
The CGS unit of kinematic viscosity was named "stokes" after his work.
Stokes' law is the basis of the falling-sphere viscometer, in which the fluid is stationary in a vertical glass tube. A sphere of known size and density is allowed to descend through the liquid. If correctly selected, it reaches terminal velocity, which can be measured by the time it takes to pass two marks on the tube. Electronic sensing can be used for opaque fluids. Knowing the terminal velocity, the size and density of the sphere, and the density of the liquid, Stokes' law can be used to calculate the viscosity of the fluid. A series of steel ball bearings of different diameters are normally used in the classic experiment to improve the accuracy of the calculation. The school experiment uses glycerine or golden syrup as the fluid, and the technique is used industrially to check the viscosity of fluids used in processes. Several school experiments often involve varying the temperature and/or concentration of the substances used in order to demonstrate the effects this has on the viscosity. Industrial methods include many different oils, and polymer liquids such as solutions.