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Glycerine

Glycerol
Glycerol
Ball-and-stick model of glycerol
Space-filling model of glycerol
Sample of glycerine
Names
Preferred IUPAC name
Propane-1,2,3-triol
Other names
Glycerin
Glycerine
Propanetriol
1,2,3-Trihydroxypropane
1,2,3-Propanetriol
Identifiers
56-81-5 YesY
3D model (Jmol) Interactive image
ChEBI CHEBI:17522 YesY
ChEMBL ChEMBL692 YesY
ChemSpider 733 YesY
DrugBank DB04077 YesY
ECHA InfoCard 100.000.263
E number E422 (thickeners, ...)
5195
KEGG D00028 YesY
PubChem 753
UNII PDC6A3C0OX YesY
Properties
C3H8O3
Molar mass 92.09 g·mol−1
Appearance colorless liquid
hygroscopic
Odor odorless
Density 1.261 g/cm3
Melting point 17.8 °C (64.0 °F; 290.9 K)
Boiling point 290 °C (554 °F; 563 K)
miscible
Vapor pressure 0.003 mmHg (50°C)
-57.06·10−6 cm3/mol
1.4746
Viscosity 1.412 Pa·s
Pharmacology
A06AG04 (WHO) A06AX01 (WHO), QA16QA03 (WHO)
Hazards
Safety data sheet See: data page
JT Baker
NFPA 704
Flammability code 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g., canola oil Health code 1: Exposure would cause irritation but only minor residual injury. E.g., turpentine Reactivity code 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g., liquid nitrogen Special hazards (white): no codeNFPA 704 four-colored diamond
Flash point 160 °C (320 °F; 433 K) (closed cup)
176 °C (349 °F; 449 K) (open cup)
US health exposure limits (NIOSH):
PEL (Permissible)
TWA 15 mg/m3 (total) TWA 5 mg/m3 (resp)
REL (Recommended)
None established
IDLH (Immediate danger)
N.D.
Supplementary data page
Refractive index (n),
Dielectric constantr), etc.
Thermodynamic
data
Phase behaviour
solid–liquid–gas
UV, IR, NMR, MS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
YesY  (what is YesYN ?)
Infobox references

Glycerol /ˈɡlɪsərɒl/ (also called glycerine or glycerin; see spelling differences) is a simple polyol compound. It is a colorless, odorless, viscous liquid that is sweet-tasting and non-toxic. The glycerol backbone is found in all lipids known as triglycerides. It is widely used in the food industry as a sweetener and humectant and in pharmaceutical formulations. Glycerol has three hydroxyl groups that are responsible for its solubility in water and its hygroscopic nature.

Although achiral, glycerol is prochiral with respect to reactions of one of the two primary alcohols. Thus, in substituted derivatives, the stereospecific numbering labels each carbon as either sn-1, sn-2, or sn-3.

Glycerol is generally obtained from plant and animal sources where it occurs as triglycerides. Triglycerides are esters of glycerol with long-chain carboxylic acids. The hydrolysis, saponification, or transesterification of these triglycerides produces glycerol as well as the fatty acid derivative:

Triglycerides (1) are treated with an alcohol such as ethanol (2) with catalytic base to give ethyl esters of fatty acids (3) and glycerol (4):


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Wikipedia

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