Stoichiometric air ratio
Air–fuel ratio (AFR) is the mass ratio of air to a solid, liquid, or gaseous fuel present in a combustion process. The combustion may take place in a controlled manner such as in an internal combustion engine or industrial furnace, or may result in an explosion (e.g., a dust explosion, gas or vapour explosion or in a thermobaric weapon).
The air-fuel ratio determines whether a mixture is combustible at all, how much energy is being released, and how much unwanted pollutants are produced in the reaction. Typically a range of fuel to air ratios exists, outside of which ignition will not occur. These are known as the lower and upper explosive limits.
In an internal combustion engine or industrial furnace, the air-fuel ratio is an important measure for anti-pollution and performance-tuning reasons. If exactly enough air is provided to completely burn all of the fuel, the ratio is known as the stoichiometric mixture, often abbreviated to stoich. Ratios lower than stoichiometric are considered "rich". Rich mixtures are less efficient, but may produce more power and burn cooler, which is kinder on the engine. Ratios higher than stoichiometric are considered "lean." Lean mixtures are more efficient but may cause engine damage or premature wear and produce higher levels of nitrogen oxides. For precise air-fuel ratio calculations, the oxygen content of combustion air should be specified because of possible dilution by ambient water vapor, or enrichment by oxygen additions.
In theory a stoichiometric mixture has just enough air to completely burn the available fuel. In practice this is never quite achieved, due primarily to the very short time available in an internal combustion engine for each combustion cycle. Most of the combustion process completes in approximately 4–5 milliseconds at an engine speed of 6,000 revolutions per minute. (100 revolutions per second; 10 milliseconds per revolution) This is the time that elapses from when the spark is fired until the burning of the fuel–air mix is essentially complete after some 80 degrees of crankshaft rotation later. Catalytic converters are designed to work best when the exhaust gases passing through them are the result of nearly perfect combustion.
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