The Stern–Gerlach experiment demonstrated that the spatial orientation of angular momentum is quantized. It demonstrated that atomic-scale systems have intrinsically quantum properties, and that measurement in quantum mechanics affects the system being measured. In the original experiment, silver atoms were sent through a non-uniform magnetic field, which deflected them before they struck a detector screen. Other kinds of particles can be used. If the particles have a magnetic moment related to their spin angular momentum, the magnetic field gradient deflects them from a straight path. The screen reveals discrete points of accumulation rather than a continuous distribution, owing to the quantum nature of spin. Historically, this experiment was decisive in convincing physicists of the reality of angular momentum quantization in all atomic-scale systems.
The experiment was first conducted by the German physicists Otto Stern and Walther Gerlach, in 1922.
The Stern–Gerlach experiment involves sending a beam of particles through an inhomogeneous magnetic field and observing their deflection. The results show that particles possess an intrinsic angular momentum that is closely analogous to the angular momentum of a classically spinning object, but that takes only certain quantized values. Another important result is that only one component of a particle's spin can be measured at one time, meaning that the measurement of the spin along the z-axis destroys information about a particle's spin along the x and y axis.
The experiment is normally conducted using electrically neutral particles or atoms. This avoids the large deflection to the orbit of a charged particle moving through a magnetic field and allows spin-dependent effects to dominate. For example, observation of the Stern–Gerlach effect with free electrons is infeasible. If the particle is treated as a classical spinning dipole, it will precess in a magnetic field because of the torque that the magnetic field exerts on the dipole (see torque-induced precession). If it moves through a homogeneous magnetic field, the forces exerted on opposite ends of the dipole cancel each other out and the trajectory of the particle is unaffected. However, if the magnetic field is inhomogeneous then the force on one end of the dipole will be slightly greater than the opposing force on the other end, so that there is a net force which deflects the particle's trajectory. If the particles were classical spinning objects, one would expect the distribution of their spin angular momentum vectors to be random and continuous. Each particle would be deflected by a different amount, producing some density distribution on the detector screen. Instead, the particles passing through the Stern–Gerlach apparatus are deflected either up or down by a specific amount. This was a measurement of the quantum observable now known as spin angular momentum, which demonstrated possible outcomes of a measurement where the observable has a discrete set of values or point spectrum. Although some discrete quantum phenomena, such as atomic spectra, were observed much earlier, the Stern–Gerlach experiment allowed scientists to observe separation between discrete quantum states for the first time in the history of science.