Spinning (polymers)

Spinning is a manufacturing process for creating polymer fibers. It is a specialized form of extrusion that uses a spinneret to form multiple continuous filaments. There are many types of spinning: wet, dry, dry jet-wet, melt, gel, and electrospinning.

First, the polymer being spun must be converted into a fluid state. If the polymer is a thermoplastic then it can be simply melted, otherwise it is dissolved in a solvent or chemically treated to form soluble or thermoplastic derivatives. The molten polymer is then forced through the spinneret, then it cools to a rubbery state, and then a solidified state. If a polymer solution is used, then the solvent is removed after being forced through the spinneret.

Wet spinning is the oldest of the five processes. This process is used for polymers that need to be dissolved in a solvent to be spun. The spinneret is submerged in a chemical bath that causes the fiber to precipitate, and then solidify, as it emerges. The process gets its name from this "wet" bath. Acrylic, rayon, aramid, modacrylic, and spandex are produced via this process.

A variant of wet spinning is dry jet-wet spinning, where the solution is extruded into air and drawn, and then submerged into a liquid bath. This method is used in Lyocell spinning of dissolved cellulose.

Dry spinning is also used for polymers that must be dissolved in solvent. It differs in that the solidification is achieved through evaporation of the solvent. This is usually achieved by a stream of air or inert gas. Because there is no precipitating liquid involved, the fiber does not need to be dried, and the solvent is more easily recovered. Acetate, triacetate, acrylic, modacrylic, polybenzimidazole fiber, spandex, and vinyon are produced via this process.

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