Names | |
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Other names
Disodium sulfide
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Identifiers | |
1313-82-2 1313-84-4 (pentahydrate) 1313-84-4 (nonahydrate) |
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3D model (Jmol) | Interactive image |
ChEBI | CHEBI:76208 |
ChemSpider | 14120 |
ECHA InfoCard | 100.013.829 |
EC Number | 215-211-5 |
PubChem | 237873 |
RTECS number | WE1905000 |
UN number | 1385 (anhydrous) 1849 (hydrate) |
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Properties | |
Na2S | |
Molar mass | 78.0452 g/mol (anhydrous) 240.18 g/mol (nonahydrate) |
Appearance | colorless, hygroscopic solid |
Odor | rotten eggs |
Density | 1.856 g/cm3 (anhydrous) 1.58 g/cm3 (pentahydrate) 1.43 g/cm3 (nonohydrate) |
Melting point | 1,176 °C (2,149 °F; 1,449 K) (anhydrous) 100 °C (pentahydrate) 50 °C (nonahydrate) |
12.4 g/100 mL (0 °C) 18.6 g/100 mL (20 °C) 39 g/100 mL (50 °C) |
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Solubility | insoluble in ether slightly soluble in alcohol |
−39.0·10−6 cm3/mol | |
Structure | |
Antifluorite (cubic), cF12 | |
Fm3m, No. 225 | |
Tetrahedral (Na+); cubic (S2−) | |
Hazards | |
Safety data sheet | ICSC 1047 |
EU classification (DSD)
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Corrosive (C) Dangerous for the environment (N) |
R-phrases | R31, R34, R50 |
S-phrases | (S1/2), S26, S45, S61 |
NFPA 704 | |
> 480 °C (896 °F; 753 K) | |
Related compounds | |
Other anions
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Sodium oxide Sodium selenide Sodium telluride |
Other cations
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Lithium sulfide Potassium sulfide |
Related compounds
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Sodium hydrosulfide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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what is ?) | (|
Infobox references | |
Sodium sulfide is the chemical compound with the formula Na2S, or more commonly its hydrate Na2S·9H2O. Both are colorless water-soluble salts that give strongly alkaline solutions. When exposed to moist air, Na2S and its hydrates emit hydrogen sulfide, which smells like rotten eggs. Some commercial samples are specified as Na2S·xH2O, where a weight percentage of Na2S is specified. Commonly available grades have around 60% Na2S by weight, which means that x is around 3. Such technical grades of sodium sulfide have a yellow appearance owing to the presence of polysulfides. These grades of sodium sulfide are marketed as 'sodium sulfide flakes'. Although the solid is yellow, solutions of it are colorless.
Na2S adopts the antifluorite structure, which means that the Na+ centers occupy sites of the fluoride in the CaF2 framework, and the larger S2− occupy the sites for Ca2+.
Industrially Na2S is produced by carbothermic reduction of sodium sulfate often using coal:
In the laboratory, the salt can be prepared by reduction of sulfur with sodium in anhydrous ammonia or by sodium in dry THF with a catalytic amount of naphthalene (forming sodium naphthalenide):
The dissolution process can be described as follows:
Sodium sulfide can oxidize when heated to sodium carbonate and sulfur dioxide:
Oxidation with hydrogen peroxide gives sodium sulfate:
Upon treatment with sulfur, polysulfides are formed:
Sodium sulfide is primarily used in pulp and paper industry in the Kraft process.