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Silicium

Silicon,  14Si
SiliconCroda.jpg
General properties
Pronunciation
Appearance crystalline, reflective with bluish-tinged faces
Standard atomic weight (Ar, standard) [28.08428.086] conventional: 28.085
Silicon in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
C

Si

Ge
aluminiumsiliconphosphorus
Atomic number (Z) 14
Group, period group 14 (carbon group), period 3
Block p-block
Element category   metalloid
Electron configuration [Ne] 3s2 3p2
Electrons per shell
2, 8, 4
Physical properties
Phase (at STP) solid
Melting point 1687 K ​(1414 °C, ​2577 °F)
Boiling point 3538 K ​(3265 °C, ​5909 °F)
Density (near r.t.) 2.3290 g/cm3
when liquid (at m.p.) 2.57 g/cm3
Heat of fusion 50.21 kJ/mol
Heat of vaporization 383 kJ/mol
Molar heat capacity 19.789 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 1908 2102 2339 2636 3021 3537
Atomic properties
Oxidation states 4, 3, 2, 1 −1, −2, −3, −4 ​(an amphoteric oxide)
Electronegativity Pauling scale: 1.90
Ionization energies
  • 1st: 786.5 kJ/mol
  • 2nd: 1577.1 kJ/mol
  • 3rd: 3231.6 kJ/mol
  • (more)
Atomic radius empirical: 111 pm
Covalent radius 111 pm
Van der Waals radius 210 pm
Color lines in a spectral range
Miscellanea
Crystal structure face-centered diamond-cubic
Diamond cubic crystal structure for silicon
Speed of sound thin rod 8433 m/s (at 20 °C)
Thermal expansion 2.6 µm/(m·K) (at 25 °C)
Thermal conductivity 149 W/(m·K)
Electrical resistivity 2.3×103 Ω·m (at 20 °C)
Band gap 1.12 eV (at 300 K)
Magnetic ordering diamagnetic
Magnetic susceptibility −3.9·10−6 cm3/mol (298 K)
Young's modulus 130–188 GPa
Shear modulus 51–80 GPa
Bulk modulus 97.6 GPa
Poisson ratio 0.064–0.28
Mohs hardness 6.5
CAS Number 7440-21-3
History
Naming after Latin 'silex' or 'silicis', meaning flint
Prediction Antoine Lavoisier (1787)
Discovery and first isolation Jöns Jacob Berzelius (1823)
Named by Thomas Thomson (1817)
Main isotopes of silicon
Iso­tope Abun­dance Half-life (t1/2) Decay mode Pro­duct
28Si 92.2% stable
29Si 4.7% stable
30Si 3.1% stable
31Si trace 2.62 h β 31P
32Si trace 153 y β 32P
| references |
Color lines in a spectral range

Silicon is a chemical element with symbol Si and atomic number 14. A hard and brittle crystalline solid with a blue-grey metallic lustre, it is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic table, along with carbon above it and germanium, tin, and lead below. It is rather unreactive, though less so than germanium, and has a very large chemical affinity for oxygen; as such, it was first prepared and characterized in pure form only in 1823 by Jöns Jakob Berzelius.

Silicon is the eighth most common element in the universe by mass, but very rarely occurs as the pure element in the Earth's crust. It is most widely distributed in dusts, sands, planetoids, and planets as various forms of silicon dioxide (silica) or silicates. Over 90% of the Earth's crust is composed of silicate minerals, making silicon the second most abundant element in the Earth's crust (about 28% by mass) after oxygen.

Most silicon is used commercially without being separated, and often with little processing of the natural minerals. Such use includes industrial construction with clays, silica sand, and stone. Silicates are used in Portland cement for mortar and stucco, and mixed with silica sand and gravel to make concrete for walkways, foundations, and roads. They are also used in whiteware ceramics such as porcelain, and in traditional quartz-based soda-lime glass and many other specialty glasses. Silicon compounds such as silicon carbide are used as abrasives and components of high-strength ceramics.


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