Silicium
Silicon, 14Si
|
General properties |
Pronunciation |
|
Appearance |
crystalline, reflective with bluish-tinged faces |
Standard atomic weight (Ar, standard)
|
[7001280840000000000♠28.084, 7001280860000000000♠28.086] conventional: 7001280850000000000♠28.085
|
Silicon in the periodic table
|
|
Atomic number (Z) |
14 |
Group, period
|
group 14 (carbon group), period 3
|
Block |
p-block |
Element category |
metalloid
|
Electron configuration |
[Ne] 3s2 3p2
|
Electrons per shell
|
2, 8, 4 |
Physical properties |
Phase (at STP)
|
solid |
Melting point |
1687 K (1414 °C, 2577 °F) |
Boiling point |
3538 K (3265 °C, 5909 °F) |
Density (near r.t.)
|
2.3290 g/cm3
|
when liquid (at m.p.) |
2.57 g/cm3
|
Heat of fusion |
50.21 kJ/mol
|
Heat of vaporization |
383 kJ/mol |
Molar heat capacity |
19.789 J/(mol·K) |
Vapor pressure
P (Pa)
|
1 |
10 |
100 |
1 k |
10 k |
100 k |
at T (K)
|
1908 |
2102 |
2339 |
2636 |
3021 |
3537 |
|
Atomic properties |
Oxidation states |
4, 3, 2, 1 −1, −2, −3, −4 (an amphoteric oxide) |
Electronegativity |
Pauling scale: 1.90 |
Ionization energies |
- 1st: 786.5 kJ/mol
- 2nd: 1577.1 kJ/mol
- 3rd: 3231.6 kJ/mol
- (more)
|
Atomic radius |
empirical: 111 pm
|
Covalent radius |
111 pm |
Van der Waals radius |
210 pm |
|
Miscellanea |
Crystal structure |
face-centered diamond-cubic
|
Speed of sound thin rod
|
8433 m/s (at 20 °C) |
Thermal expansion |
2.6 µm/(m·K) (at 25 °C) |
Thermal conductivity |
149 W/(m·K) |
Electrical resistivity |
2.3×103 Ω·m (at 20 °C) |
Band gap |
1.12 eV (at 300 K) |
Magnetic ordering |
diamagnetic |
Magnetic susceptibility |
−3.9·10−6 cm3/mol (298 K) |
Young's modulus |
130–188 GPa |
Shear modulus |
51–80 GPa |
Bulk modulus |
97.6 GPa |
Poisson ratio |
0.064–0.28 |
Mohs hardness |
6.5 |
CAS Number |
7440-21-3 |
History |
Naming |
after Latin 'silex' or 'silicis', meaning flint
|
Prediction |
Antoine Lavoisier (1787)
|
Discovery and first isolation |
Jöns Jacob Berzelius (1823) |
Named by |
Thomas Thomson (1817)
|
Main isotopes of silicon
|
|
| references | |
Silicon is a chemical element with symbol Si and atomic number 14. A hard and brittle crystalline solid with a blue-grey metallic lustre, it is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic table, along with carbon above it and germanium, tin, and lead below. It is rather unreactive, though less so than germanium, and has a very large chemical affinity for oxygen; as such, it was first prepared and characterized in pure form only in 1823 by Jöns Jakob Berzelius.
Silicon is the eighth most common element in the universe by mass, but very rarely occurs as the pure element in the Earth's crust. It is most widely distributed in dusts, sands, planetoids, and planets as various forms of silicon dioxide (silica) or silicates. Over 90% of the Earth's crust is composed of silicate minerals, making silicon the second most abundant element in the Earth's crust (about 28% by mass) after oxygen.
Most silicon is used commercially without being separated, and often with little processing of the natural minerals. Such use includes industrial construction with clays, silica sand, and stone. Silicates are used in Portland cement for mortar and stucco, and mixed with silica sand and gravel to make concrete for walkways, foundations, and roads. They are also used in whiteware ceramics such as porcelain, and in traditional quartz-based soda-lime glass and many other specialty glasses. Silicon compounds such as silicon carbide are used as abrasives and components of high-strength ceramics.
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