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Reduced iron

Iron,  26Fe
Pure iron chips with a high purity iron cube
General properties
Pronunciation /ˈ.ərn/
EYE-urn
Appearance lustrous metallic with a grayish tinge
Standard atomic weight (Ar, std) 55.845(2)
Iron in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson


Fe

Ru
manganeseironcobalt
Atomic number (Z) 26
Group, period group 8, period 4
Block d-block
Element category   transition metal
Electron configuration [Ar] 3d6 4s2
Electrons per shell
2, 8, 14, 2
Physical properties
Phase (at STP) solid
Melting point 1811 K ​(1538 °C, ​2800 °F)
Boiling point 3134 K ​(2862 °C, ​5182 °F)
Density (near r.t.) 7.874 g/cm3
when liquid (at m.p.) 6.98 g/cm3
Heat of fusion 13.81 kJ/mol
Heat of vaporization 340 kJ/mol
Molar heat capacity 25.10 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 1728 1890 2091 2346 2679 3132
Atomic properties
Oxidation states −4, −2, −1, +1,+2, +3, +4, +5,+6, +7 ​(an amphoteric oxide)
Electronegativity Pauling scale: 1.83
Ionization energies
  • 1st: 762.5 kJ/mol
  • 2nd: 1561.9 kJ/mol
  • 3rd: 2957 kJ/mol
  • (more)
Atomic radius empirical: 126 pm
Covalent radius Low spin: 132±3 pm
High spin: 152±6 pm
Color lines in a spectral range
Miscellanea
Crystal structure body-centered cubic (bcc)
Body-centered cubic crystal structure for iron

a=286.65 pm
Crystal structure face-centered cubic (fcc)
Face-centered cubic crystal structure for iron

between 1185–1667 K
Speed of sound thin rod 5120 m/s (at r.t.) (electrolytic)
Thermal expansion 11.8 µm/(m·K) (at 25 °C)
Thermal conductivity 80.4 W/(m·K)
Electrical resistivity 96.1 nΩ·m (at 20 °C)
Curie point 1043 K
Magnetic ordering ferromagnetic
Young's modulus 211 GPa
Shear modulus 82 GPa
Bulk modulus 170 GPa
Poisson ratio 0.29
Mohs hardness 4
Vickers hardness 608 MPa
Brinell hardness 200–1180 MPa
CAS Number 7439-89-6
History
Discovery before 5000 BC
Main isotopes of iron
Iso­tope Abun­dance Half-life (t1/2) Decay mode Pro­duct
54Fe 5.85% stable
55Fe syn 2.73 y ε 55Mn
56Fe 91.75% stable
57Fe 2.12% stable
58Fe 0.28% stable
59Fe syn 44.6 d β 59Co
60Fe syn 2.6×106 y β 60Co
| references |
Color lines in a spectral range

Iron is a chemical element with symbol Fe (from Latin: ferrum) and atomic number 26. It is a metal in the first transition series. It is by mass the most common element on Earth, forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust. Its abundance in rocky planets like Earth is due to its abundant production by fusion in high-mass stars, where it is the last element to be produced with release of energy before the violent collapse of a supernova, which scatters the iron into space.

Like the other group 8 elements, ruthenium and osmium, iron exists in a wide range of oxidation states, −2 to +7, although +2 and +3 are the most common. Elemental iron occurs in meteoroids and other low oxygen environments, but is reactive to oxygen and water. Fresh iron surfaces appear lustrous silvery-gray, but oxidize in normal air to give hydrated iron oxides, commonly known as rust. Unlike the metals that form passivating oxide layers, iron oxides occupy more volume than the metal and thus flake off, exposing fresh surfaces for corrosion.


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