"Prince Charming" was a number-one single in the UK Singles Chart for four weeks in September 1981 for Adam and the Ants. Written by Adam Ant and Marco Pirroni, and featured on the album of the same name, it was Adam and the Ants' second number-one single in a row, and was the fifth biggest hit of the year 1981.

Band member and producer Merrick (Chris Hughes), normally on drums, played a stirring riff on an open-tuned acoustic guitar throughout the song. Lead guitarist Pirroni mimed to this part on both an orchestral harp and a miniature harp in the promotional video. The music video was notable for its extravagant production compared to the videos being produced at the time.

It featured Adam Ant in a male Cinderella role, complete with moustached drag queen evil step-sisters. The sisters accept an invitation to "Come to the ball, and dance the Prince Charming," leaving a dirty Adam home to do chores.

Sitting at a table in an old style kitchen, Adam is surrounded by his band members, who are encouraging him, "Don't you ever/Don't you ever/Stop being dandy, showing me you're handsome." His Fairy Godmother, portrayed by Diana Dors, suddenly appears with five shirtless men dancing the "Prince Charming." With a wave of her magic wand, she transforms Adam's attire into flamboyant Regency clothes.

Adam makes a grand entrance onto the balcony at the ball, and swings down on a chandelier. He, the Ants, his Fairy Godmother, her male accompaniment and the invited guests of the ball dance the "Prince Charming," which became a much imitated arm-crossing dance as the song rose up the charts. The video ends with Adam smashing a mirror, then singing the "Prince Charming, Prince Charming/Ridicule is nothing to be scared of" refrain as different characters: Clint Eastwood from The Good, the Bad and the Ugly, Alice Cooper, Rudolph Valentino from the silent film The Sheik,Vito Corleone (Marlon Brando) from The Godfather, and his own "Dandy highwayman" from the "Stand and Deliver" video. The music video was one of Diana Dors' last on-screen performances.

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