Polynomial chaos (PC), also called Wiener chaos expansion, is a non-sampling-based method to determine evolution of uncertainty in a dynamical system, when there is probabilistic uncertainty in the system parameters.
PC was first introduced by Norbert Wiener where Hermite polynomials were used to model processes with Gaussian random variables. It can be thought of as an extension of Volterra's theory of nonlinear functionals for stochastic systems. According to Cameron and Martin such an expansion converges in the sense for any arbitrary stochastic process with finite second moment. This applies to most physical systems.
Xiu (in his PhD under Karniadakis at Brown University) generalized the result of Cameron–Martin to various continuous and discrete distributions using orthogonal polynomials from the so-called Askey-scheme and demonstrated convergence in the corresponding Hilbert functional space. This is popularly known as the generalized polynomial chaos (gPC) framework. The gPC framework has been applied to applications including stochastic fluid dynamics, stochastic finite elements, solid mechanics, nonlinear estimation, the evaluation of finite word-length effects in non-linear fixed-point digital systems and probabilistic robust control. It has been demonstrated that gPC based methods are computationally superior to Monte-Carlo based methods in a number of applications. However, the method has a notable limitation. For large numbers of random variables, polynomial chaos becomes very computationally expensive and Monte-Carlo methods are typically more feasible.