Phenacene

Phenacenes are a class of organic compounds consisting of fused aromatic rings. They are polycyclic aromatic hydrocarbons, related to acenes and helicenes from which they differ by the arrangement of the fused rings.

Aromatic compounds with extended π-conjugated system have attracted attention because of their potential utilization in organic electronic materials. In the past decade, pentacene has been widely used as an active layer in organic thin film field effect transistors (OFET). The main drawback of pentacene OFET is degradation upon exposure to light and air. On the other hand, [n]phenacenes, an isomeric form of [n]acenes, has been known as a stable compound in which the benzene rings are fused in a zigzag structure. For the past several years, there is renewed interest in synthesis of [n]phenacene derivatives associated with electronic applications in emissive and semi- or superconducting materials.

Picene ([5]phenacene) can serve as an active layer of a high performance p-channel organic thin film FET with very high field-effect mobility: μ of 5 cm²∙V⁻¹∙s⁻¹. [7]Phenacene FET showed effect mobility μ of 0.75 cm²∙V⁻¹∙s⁻¹ and no sensitivity to air. Furthermore, picene doped with potassium and rubidium exhibit superconductivity with a maximum critical temperature ...
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