Phase inversion (chemistry)

Phase inversion is a chemical phenomenon exploited in the fabrication of artificial membranes. It is performed by removing the solvent from a liquid-polymer solution, leaving a porous, solid membrane.

Phase inversion is a common method to form filtration membranes, which are typically formed using artificial polymers. The method of phase inversion is highly dependent on the type of polymer used and the solvent used to dissolve the polymer.

Phase inversion can be carried out through one of four typical methods:

The rate at which phase inversion occurs and the characteristics of the resulting membrane are dependent on several factors, including:

Phase inversion membranes are typically characterized according pore size and pore distribution. This can be measured using evapoporometry, where the membrane is immersed in 2-propanol and measured for change in mass due to evaporation of the 2-propanol. The rate of evaporation of 2-propanol from the pores of the membrane can be used to calculate the pore size using the Kelvin equation. A Scanning electron microscope (SEM) can be used to characterize membranes with larger pore sizes, such as microfiltration and ultrafiltration membranes, while Transmission electron microscopy (TEM) can be used for all membrane types, including small pore membranes such as nanofiltration and reverse osmosis.

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