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Names | |||
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IUPAC name
Tetrachloroethene
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Other names
Perchloroethene; Perchloroethylene; Perc; PCE
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Identifiers | |||
3D model (Jmol)
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ChEBI | |||
ChemSpider | |||
ECHA InfoCard | 100.004.388 | ||
EC Number | 204-825-9 | ||
KEGG | |||
RTECS number | KX3850000 | ||
UNII | |||
UN number | 1897 | ||
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Properties | |||
C2Cl4 | |||
Molar mass | 165.82 g·mol−1 | ||
Appearance | Clear, colorless liquid | ||
Odor | mild, chloroform-like | ||
Density | 1.622 g/cm3 | ||
Melting point | −19 °C (−2 °F; 254 K) | ||
Boiling point | 121.1 °C (250.0 °F; 394.2 K) | ||
0.15 g/L (25 °C) | |||
Vapor pressure | 14 mmHg (20°C) | ||
-81.6·10−6 cm3/mol | |||
Viscosity | 0.89 cP at 25 °C | ||
Hazards | |||
Main hazards | Harmful (Xn), Dangerous for the environment (N) |
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Safety data sheet |
See: data page External MSDS |
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R-phrases | R40 R51/53 | ||
S-phrases | S23 S36/37 S61 | ||
NFPA 704 | |||
Flash point | Not flammable | ||
Lethal dose or concentration (LD, LC): | |||
LC50 (median concentration)
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4000 ppm (rat, 4 hr) 5200 ppm (mouse, 4 hr) 4964 ppm (rat, 8 hr) |
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US health exposure limits (NIOSH): | |||
PEL (Permissible)
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TWA 100 ppm C 200 ppm (for 5 minutes in any 3-hour period), with a maximum peak of 300 ppm |
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REL (Recommended)
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Ca Minimize workplace exposure concentrations. | ||
IDLH (Immediate danger)
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Ca [150 ppm] | ||
Related compounds | |||
Related Related organohalides
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Tetrabromoethylene Tetraiodoethylene |
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Related compounds
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Trichloroethylene Dichloroethene Tetrachloroethane |
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Supplementary data page | |||
Refractive index (n), Dielectric constant (εr), etc. |
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Thermodynamic
data |
Phase behaviour solid–liquid–gas |
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UV, IR, NMR, MS | |||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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what is ?) | (|||
Infobox references | |||
Tetrachloroethylene, also known under the systematic name tetrachloroethene, or perchloroethylene ("perc" or "PERC"), and many other names, is a chlorocarbon with the formula Cl2C=CCl2. It is a colorless liquid widely used for dry cleaning of fabrics, hence it is sometimes called "dry-cleaning fluid." It has a sweet odor detectable by most people at a concentration of 1 part per million (1 ppm). Worldwide production was about 1 million metric tons (980,000 long tons; 1,100,000 short tons) in 1985.
Michael Faraday first synthesized tetrachloroethylene in 1821 by thermal decomposition of hexachloroethane.
Most tetrachloroethylene is produced by high temperature chlorinolysis of light hydrocarbons. The method is related to Faraday's discovery since hexachloroethane is generated and thermally decomposes. Side products include carbon tetrachloride, hydrogen chloride, and hexachlorobutadiene.
Several other methods have been developed. When 1,2-dichloroethane is heated to 400 °C with chlorine, tetrachloroethylene is produced by the chemical reaction:
This reaction can be catalyzed by a mixture of potassium chloride and aluminium chloride or by activated carbon. Trichloroethylene is a major byproduct, which is separated by distillation.
According to a United States Environmental Protection Agency (EPA) report of 1976, the quantity of tetrachloroethylene produced in the United States in 1973 totaled 320,000 metric tons (706 million lb). By 1993, the volume produced in the United States had dropped to 123,000 metric tons (271 million lb).