Nitrogen fixation

Nitrogen fixation is a process by which nitrogen (N₂) in the Earth's atmosphere is converted into ammonia (NH₃). Atmospheric nitrogen or molecular dinitrogen (N₂) is relatively inert: it does not easily react with other chemicals to form new compounds. The fixation process frees nitrogen atoms from their triply bonded diatomic form, N≡N, to be used in other ways.

Nitrogen fixation, natural and synthetic, is essential for all forms of life because nitrogen is required to biosynthesize basic building blocks of plants, animals and other life forms, e.g., nucleotides for DNA and RNA, the coenzyme nicotinamide adenine dinucleotide for its role in metabolism (transferring electrons between molecules), and amino acids for proteins. Therefore, as part of the nitrogen cycle, it is essential for agriculture and the manufacture of fertilizer. It is also, indirectly, relevant to the manufacture of all chemical compounds that contain nitrogen, which includes explosives, most pharmaceuticals, dyes, etc. Nitrogen fixation occurs naturally in the soil by nitrogen fixing bacteria (for example, Azotobacter affiliated with some plants, especially legumes). Some nitrogen-fixing bacteria have very close relationships with plants, referred to as symbiotic nitrogen fixation. Looser relationships between nitrogen-fixing bacteria and plants are often referred to as associative or non-symbiotic, as seen in nitrogen fixation occurring on rice roots. It also occurs naturally in the air by means of lightning.

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