Prince Nikolai Dmitriyevich Golitsyn (Russian: Никола́й Дми́триевич Голи́цын; 12 April 1850 – 2 July 1925) was of Russian nobility and was the last prime minister of Imperial Russia. He served from 29 December 1916 (O.S.) or 9 January 1917 (N.S.) until his government resigned after the outbreak of the February Revolution.
Golitsyn was born in Porechye, a village in the Mozhaysky District, Moscow Oblast into the noble Golitsyn family, but passed his childhood in the Dorogobuzhsky District. He was a graduate of the Imperial Alexander Lyceum in 1871 and entered the Ministry of the Interior and appointed in Łomża Governorate (Congress Poland). He became vice-governor of Archangelsk (1879); vice-director of the Economic Department of the Ministry of Internal Affairs (1884); Governor of the guberniyas of Arkhangelsk (1885), Kaluga (1893), and Tver (1897). He was appointed Senator in 1903. As a plenipotentiary of the Red Cross in Turgay and Uralskaya Oblasts and Saratov Governorate he organized help to the famine-stricken areas (1907-1908). He was member of the State Council (1912) and chairman of the commission to render assistance to the Russian prisoners of war abroad (1915). His advanced years led him to regularly fall asleep during State Council meetings. He was a deputy chairman of one of Empress Alexandra's charity commissions.