A neo-Hookean solid is a hyperelastic material model, similar to Hooke's law, that can be used for predicting the nonlinear stress-strain behavior of materials undergoing large deformations. The model was proposed by Ronald Rivlin in 1948. In contrast to linear elastic materials, the stress-strain curve of a neo-Hookean material is not linear. Instead, the relationship between applied stress and strain is initially linear, but at a certain point the stress-strain curve will plateau. The neo-Hookean model does not account for the dissipative release of energy as heat while straining the material and perfect elasticity is assumed at all stages of deformation.
The neo-Hookean model is based on the statistical thermodynamics of cross-linked polymer chains and is usable for plastics and rubber-like substances. Cross-linked polymers will act in a neo-Hookean manner because initially the polymer chains can move relative to each other when a stress is applied. However, at a certain point the polymer chains will be stretched to the maximum point that the covalent cross links will allow, and this will cause a dramatic increase in the elastic modulus of the material. The neo-Hookean material model does not predict that increase in modulus at large strains and is typically accurate only for strains less than 20%. The model is also inadequate for biaxial states of stress and has been superseded by the Mooney-Rivlin model.
The strain energy density function for an incompressible neo-Hookean material in a three-dimensional description is
where is a material constant, and is the first invariant of the right Cauchy-Green deformation tensor, i.e.,