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Methanediol

Methanediol
Skeletal formula of methanediol with some explicit hydrogens added
Spacefill model of methanediol
Ball and stick model of the methanediol
Names
IUPAC name
Methanediol
Other names
  • Formald hydrate
  • Formaldehyde monohydrate
  • Methylene glycol
Identifiers
463-57-0 YesY
3D model (Jmol) Interactive image
Abbreviations MADOL
1730798
ChEBI CHEBI:48397 YesY
ChemSpider 71348 YesY
ECHA InfoCard 100.006.673
EC Number 207-339-5
PubChem 79015
Properties
CH4O2
Molar mass 48.04 g·mol−1
Appearance Colourless liquid
Density 1.199 g cm−3
Boiling point 194 °C (381 °F; 467 K) at 101 kPa
Vapor pressure 16.1 Pa
Acidity (pKa) 13.29
1.401
Hazards
Flash point 99.753 °C (211.555 °F; 372.903 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
YesY  (what is YesYN ?)
Infobox references

Methanediol, also known as formaldehyde monohydrate or methylene glycol, is an organic compound with chemical formula CH2(OH)2. It is the simplest geminal diol, and formally the second simplest carbohydrate (after formaldehyde).

Methanediol is a product of the hydration of formaldehyde H2C=O, and predominates in water solution: the equilibrium constant being about 103, and in a 5% by weight solution of formaldehyde in water, 80% is in the methanediol form.

The compound is of some relevance to astrochemistry.

Methanediol is listed as one of the main ingredients of "Brazilian blowout", a hair-straightening formula marketed in the US. The equilibrium with formaldehyde may cause some concern as formaldehyde in hair straighteners is a health hazard.


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