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Lammerite

Copper(II) arsenate
Copper(II)-arsenate-constituent-ions-2D.png
Names
IUPAC name
Copper(II) arsenate
Other names
Copper arsenate
Identifiers
7778-41-8 YesY
3D model (Jmol) Interactive image
ChemSpider 24279 YesY
PubChem 26065
Properties
Cu3(AsO4)2
Molar mass 468.48 g/mol
Appearance blue or bluish green powder
Density 5.2 g/cm3
Melting point 1,100 °C (2,010 °F; 1,370 K)
insoluble
Solubility soluble in ammonia, dilute acids
Hazards
US health exposure limits (NIOSH):
PEL (Permissible)
TWA 1 mg/m3 (as Cu)
REL (Recommended)
TWA 1 mg/m3 (as Cu)
IDLH (Immediate danger)
TWA 100 mg/m3 (as Cu)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
YesY  (what is YesYN ?)
Infobox references

Copper arsenate (Cu3(AsO4)2.4H2O, or Cu5H2(AsO4)4.2H2O), also called copper orthoarsenate, tricopper arsenate, cupric arsenate, or tricopper orthoarsenate, is a blue or bluish-green powder insoluble in water and alcohol and soluble in aqueous ammonium and dilute acids. Its CAS number is 7778-41-8 or 10103-61-4.

Copper arsenate is an insecticide used in agriculture. It is also used as a herbicide, fungicide, and a rodenticide. It is also used as a poison in slug baits.

Copper arsenate can also be a misnomer for copper arsenite, especially when meant as a pigment.

Anhydrous copper arsenate, Cu3(AsO4)2, is found in nature as the mineral lammerite. Copper arsenate tetrahydrate, Cu3(AsO4)2.4H2O, occurs naturally as the mineral rollandite.

Copper arsenate hydroxide or basic copper arsenate (Cu(OH)AsO4) is a basic variant with CAS number 16102-92-4. It is found naturally as the mineral olivenite. It is used as an insecticide, fungicide, and miticide. Its use is banned in Thailand since 2001.


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