Iron Age metallurgy

Ferrous metallurgy involves processes and alloys based on iron. It began far back in prehistory. The earliest surviving iron artifacts, from the 4th millennium BC in Egypt, were made from meteoritic iron-nickel. It is not known when or where the smelting of iron from ores began, but by the end of the 2nd millennium BC iron was being produced from iron ores from China to Sub-Saharan Africa. The use of wrought iron (worked iron) was known by the 1st millennium BC. During the medieval period, means were found in Europe of producing wrought iron from cast iron (in this context known as pig iron) using finery forges. For all these processes, charcoal was required as fuel.

Steel (with a carbon content between pig iron and wrought iron) was first produced in antiquity as an alloy. Its process of production, Wootz steel, was exported before the 4th century BC to ancient China, Africa, the Middle East and Europe. Archaeological evidence of cast iron appears in 5th century BC China. New methods of producing it by carburizing bars of iron in the cementation process were devised in the 17th century. During the Industrial Revolution, new methods of producing bar iron without charcoal were devised and these were later applied to produce steel. In the late 1850s, Henry Bessemer invented a new steelmaking process, that involved blowing air through molten pig iron to burn off carbon, and so to produce mild steel. This and other 19th-century and later processes have displaced the use of wrought iron. Today, wrought iron is no longer produced on a commercial scale.

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