Helium-3
Helium-3 (He-3, also written as 3He, see also helion) is a light, non-radioactive isotope of helium with two protons and one neutron (common helium having two neutrons). Its hypothetical existence was first proposed in 1934 by the Australian nuclear physicist Mark Oliphant while he was working at the University of Cambridge Cavendish Laboratory. Oliphant had performed experiments in which fast deuterons collided with deuteron targets (incidentally, the first demonstration of nuclear fusion). Helium-3 was thought to be a radioactive isotope until it was also found in samples of natural helium, which is mostly helium-4, taken both from the terrestrial atmosphere and from natural gas wells. Other than 1H, helium-3 is the only stable isotope of any element with more protons than neutrons.
Helium-3 occurs as a primordial nuclide, escaping from the Earth's crust into the atmosphere and into outer space over millions of years. Helium-3 is also thought to be a natural nucleogenic and cosmogenic nuclide, one produced when lithium is bombarded by natural neutrons, which can be released by spontaneous fission and by nuclear reactions with cosmic rays. Some of the helium-3 found in the terrestrial atmosphere is also a relic of atmospheric and underwater nuclear weapons testing. Most of this comes from the decay of tritium (hydrogen-3), which decays into helium-3 with a half life of 12.3 years. Furthermore, some nuclear reactors (landbound or shipbound) periodically release some helium-3 and tritium into the atmosphere. The nuclear reactor disaster at Chernobyl released a huge amount of radioactive tritium into the atmosphere, and smaller accidents have caused smaller releases. Furthermore, significant amounts of tritium and helium-3 have been deliberately produced in national arsenal nuclear reactors by the irradiation of lithium-6. The tritium is used to "boost" nuclear weapons, and some of this inevitably escapes during its production, transportation, and storage. Hence, helium-3 enters the atmosphere both through its direct release and through the radioactive decay of tritium.