Green rust is a generic name for various green crystalline chemical compounds containing iron(II) and iron(III) cations, the hydroxide (HO−
) anion, and another anion such as carbonate (CO2−
3), chloride (Cl−
), or sulfate (SO2−
4), in a layered double hydroxide structure. The most studied varieties are
Other varieties reported in the literature have bromide Br−
,fluoride F−
,iodide I−
,nitrate NO−
3, and selenate.
Green rust was first recognized as a corrosion crust on iron and steel surfaces. It occurs in nature as the mineral fougerite.