George Melville, 1st Earl of Melville (1636 – 20 May 1707) was a Scots and statesman during the reigns of William and Mary.
In 1643, he succeeded his father as Lord Melville.
At the Restoration of the Stuarts Melville was a moderate Whig and Presbyterian who whilst serving under the Duke of Monmouth in his suppression of the Covenanters in 1679 had tried to persuade the insurgents (Whig extremists) to lay down their arms peacefully.
The turning point in his career came in 1683 when Melville and his son David Leslie-Melville, the Earl of Leven, were accused of complicity in the Rye House Plot — a Whig conspiracy to assassinate King Charles II and his brother the Duke of York (the future James VII).
To escape arrest Melville, together with his son, Leven fled to the Netherlands where they joined the band of British Protestant exiles at the court of Prince William of Orange. Here Melville became one of the chief Scots supporters of William of Orange.
After the "Glorious Revolution" of 1688 Melville played a prominent part in Scots and English politics, most notably in the Convention Parliament which offered the crown of Scotland to William of Orange and his wife, Mary, daughter of the deposed James VII. In 1689 William made him sole Secretary of State for Scotland and in 1690 he was created Earl of Melville, Viscount Kirkaldie, and Lord Raith, Monymaill and Balwearie (all in the Peerage of Scotland).