Names | |
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IUPAC name
Sodium hydrogen phosphate
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Other names
Disodium hydrogen orthophosphate
Sodium hydrogen phosphate Sodium phosphate dibasic disodium phosphate |
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Identifiers | |
7558-79-4 10028-24-7 (dihydrate) 7782-85-6 (heptahydrate) 10039-32-4 (dodecahydrate) |
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3D model (Jmol) | Interactive image |
ChEBI | CHEBI:34683 |
ChEMBL | ChEMBL1060 |
ChemSpider | 22625 |
ECHA InfoCard | 100.028.590 |
EC Number | 231-448-7 |
PubChem | 24203 |
RTECS number | WC4500000 |
UNII | 22ADO53M6F |
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Properties | |
Na2HPO4 | |
Molar mass | 141.96 g/mol (anhydrous) 268.07 g/mol (heptahydrate) |
Appearance | White crystalline solid |
Odor | odorless |
Density | 1.7 g/cm3 |
Melting point | 250 °C (482 °F; 523 K) decomposes |
7.7 g/100 ml (20 °C) 11.8 g/100 mL (25 °C, heptahydrate) |
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Solubility | insoluble in alcohol |
log P | -5.8 |
Acidity (pKa) | 12.35 |
−56.6·10−6 cm3/mol | |
Refractive index (nD)
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1.35644..1.35717 at 20°C |
Hazards | |
Main hazards | Irritant |
Safety data sheet | ICSC 1129 |
NFPA 704 | |
Flash point | Non-flammable |
Lethal dose or concentration (LD, LC): | |
LD50 (median dose)
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17000 mg/kg (rat, oral) |
Related compounds | |
Other anions
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sodium phosphite |
Other cations
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Dipotassium phosphate Diammonium phosphate |
Related compounds
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Monosodium phosphate Trisodium phosphate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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what is ?) | (|
Infobox references | |
Disodium phosphate (DSP), or sodium hydrogen phosphate, is the inorganic compound with the formula Na2HPO4. It is one of several sodium phosphates. The salt is known in anhydrous form as well as forms with 2, 7, 8, and 12 hydrates. All are water-soluble white powders; the anhydrous salt being hygroscopic.
The pH of disodium hydrogen phosphate water solution is between 8.0 and 11.0, meaning it is moderately basic:
It can be generated by neutralization of phosphoric acid with sodium hydroxide:
Industrially It is prepared in a two-step process by treating dicalcium phosphate with sodium bisulfate, which precipitates calcium sulfate:
In the second step, the resulting solution of monosodium phosphate is partially neutralized:
It is used in conjunction with trisodium phosphate in foods and water softening treatment. In foods, it is used to adjust pH. Its presence prevents coagulation in the preparation of condensed milk. Similarly, it is used as an anti-caking additive in powdered products. It is used in desserts and puddings, e.g. Cream of Wheat to quicken cook time, and Jell-O Instant Pudding for thickening. In water treatment, it retards calcium scale formation. It is also found in some detergents and cleaning agents.
Heating solid disodium phosphate gives the useful compound tetrasodium pyrophosphate:
Monobasic and dibasic sodium phosphate are used as a saline laxative to treat constipation or to clean the bowel before a colonoscopy.