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Difluorine

Fluorine,  9F
Small sample of pale yellow liquid fluorine condensed in liquid nitrogen
Liquid fluorine (at extremely low temperatures)
General properties
Pronunciation /ˈflʊərn/, /ˈflʊərɪn/, /ˈflɔərn/
FLOOR-een, FLOOR-in, FLOHR-een
Allotropes alpha, beta
Appearance gas: very pale yellow
liquid: bright yellow
solid: alpha is opaque, beta is transparent
Standard atomic weight (Ar, std) 18.998403163(6)
Fluorine in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson


F

Cl
oxygenfluorineneon
Atomic number (Z) 9
Group, period group 17 (halogens), period 2
Block p-block
Element category   diatomic nonmetal
Electron configuration [He] 2s2 2p5
Electrons per shell
2, 7
Physical properties
Phase (at STP) gas
Melting point 53.48 K ​(−219.67 °C, ​−363.41 °F)
Boiling point 85.03 K ​(−188.11 °C, ​−306.60 °F)
Density (at STP) 1.696 g/L
when liquid (at b.p.) 1.505 g/cm3
Triple point 53.48 K, ​90 kPa
Critical point 144.41 K, 5.1724 MPa
Heat of vaporization 6.51 kJ/mol
Molar heat capacity Cp: 31 J/(mol·K) (at 21.1 °C)
Cv: 23 J/(mol·K) (at 21.1 °C)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 38 44 50 58 69 85
Atomic properties
Oxidation states −1 ​(oxidizes oxygen)
Electronegativity Pauling scale: 3.98
Ionization energies
  • 1st: 1681 kJ/mol
  • 2nd: 3374 kJ/mol
  • 3rd: 6147 kJ/mol
  • (more)
Covalent radius 64 pm
Van der Waals radius 135 pm
Color lines in a spectral range
Miscellanea
Crystal structure cubic
Cubic crystal structure for fluorine
Thermal conductivity 0.02591 W/(m·K)
Magnetic ordering diamagnetic (−1.2×10−4)
CAS Number 7782-41-4
History
Naming after the mineral fluorite, itself named after Latin fluo (to flow, in smelting)
Discovery André-Marie Ampère (1810)
First isolation Henri Moissan(June 26, 1886)
Named by Humphry Davy
Main isotopes of fluorine
Iso­tope Abun­dance Half-life (t1/2) Decay mode Pro­duct
18F trace 109.77 min β+ (96.9%) 18O
ε (3.1%) 18O
19F 100% stable
| references |
Color lines in a spectral range
External video
Bright flames during fluorine reactions
Fluorine reacting with caesium

Fluorine is a chemical element with symbol F and atomic number 9. It is the lightest halogen and exists as a highly toxic pale yellow diatomic gas at standard conditions. As the most electronegative element, it is extremely reactive: almost all other elements, including some noble gases, form compounds with fluorine.

Among the elements, fluorine ranks 24th in universal abundance and 13th in terrestrial abundance. Fluorite, the primary mineral source of fluorine which gave the element its name, was first described in 1529; as it was added to metal ores to lower their melting points for smelting, the Latin verb fluo meaning "flow" gave the mineral its name. Proposed as an element in 1810, fluorine proved difficult and dangerous to separate from its compounds, and several early experimenters died or sustained injuries from their attempts. Only in 1886 did French chemist Henri Moissan isolate elemental fluorine using low-temperature electrolysis, a process still employed for modern production. Industrial production of fluorine gas for uranium enrichment, its largest application, began during the Manhattan Project in World War II.

Owing to the expense of refining pure fluorine, most commercial applications use fluorine compounds, with about half of mined fluorite used in steelmaking. The rest of the fluorite is converted into corrosive hydrogen fluoride en route to various organic fluorides, or into cryolite which plays a key role in aluminium refining. Organic fluorides have very high chemical and thermal stability; their major uses are as refrigerants, electrical insulation and cookware, the last as PTFE (Teflon). Pharmaceuticals such as atorvastatin and fluoxetine also contain fluorine, and the fluoride ion inhibits dental cavities, and so finds use in toothpaste and water fluoridation. Global fluorochemical sales amount to more than US$15 billion a year.


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